4-(2-Chloroethoxy)phthalonitrile
نویسندگان
چکیده
In the title compound, C(10)H(7)ClN(2)O, the O and both C atoms of the chloroethoxy group are disordered over two positions, the occupancy factor of the major disorder component refining to 0.54 (2).
منابع مشابه
4-{2-Methoxy-6-[(4-methylphenyl)iminomethyl]phenoxy}phthalonitrile
In the mol-ecule of the title compound, C(23)H(17)N(3)O(2), the methoxy-phenyl ring is oriented at dihedral angles of 13.34 (12) and 88.83 (12)° with respect to the methyl-phenyl and phthalonitrile rings, respectively; the dihedral angle between methyl-phenyl and phthalonitrile rings is 89.67 (10)°. In the crystal structure, weak inter-molecular C-H⋯N inter-actions link mol-ecules into chains. ...
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In the title compound, C(21)H(12)ClN(3)O, the phenoxy ring makes dihedral angles of 51.42 (5) and 65.01 (6)°, respectively, with the chlorophenyl and phthalonitrile rings. In the crystal structure, the mol-ecules are inter-linked through weak C-H⋯N and C-H⋯π contacts, and π-π stacking inter-actions via crystallographic inversion centres form a three-dimensional network. The distance between the...
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In the title compound, C(36)H(44)N(2)O(2), the dihedral angles between the phthalonitrile ring and the two di-tert-butyl-benzene rings are 68.134 (8) and 70.637 (11)°. The two nitrile groups are almost coplanar with the phthalonitrile ring except for one of the N atoms which deviates from the plane by 0.125 (4) Å. One of the tert-butyl groups is disordered over two orientations, with refined oc...
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Synthesis of metal-free and metallophthalocyanines bearing a-methylferrocenylmethoxy units was described. Precursor 3 required for the preparation of phthalocyanines 4–9, was synthsized by the nucleophilic aromatic substitution reaction between a-methylferrocenylmethanol and 4-nitrophthalonitrile in dry DMF. The metal-free phthalocyanine 4 was prepared from 4-(amethylferrocenylmethoxy)phthaloni...
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The title compound, C(22)H(15)ClO(4), containing three chiral C atoms, is an inter-mediate in the design of chiral alcohols. In the crystal structure, a chain structure is generated through C-H⋯O contacts and an intramolecular C-H⋯O interaction also occurs. The dihedral angle between the benzene ring and the naphthalene system is 16.5°.
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